南海冷水竹节珊瑚碳-氧稳定同位素分馏机制

朱玉晗, 陈桑, 黄恩清, 党皓文, 周晓理, 江小英

海洋学研究 ›› 2026, Vol. 44 ›› Issue (3) : 91-101.

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海洋学研究 ›› 2026, Vol. 44 ›› Issue (3) : 91-101. DOI: 10.27049/j.cnki.1001-909X.2026027
研究论文

南海冷水竹节珊瑚碳-氧稳定同位素分馏机制

作者信息 +

Fractionation mechanism of stable carbon and oxygen isotopes in cold-water bamboo corals from the South China Sea

Author information +
文章历史 +

摘要

冷水竹节珊瑚钙质(方解石质)骨骼的稳定碳-氧同位素可作为古海水温度计,然而其同位素分馏机制尚不明确,制约了该指标的古环境重建精度和应用范围。本研究通过测定南海竹节珊瑚骨骼的碳-氧同位素组成,发现其拟合线斜率与已报道的太平洋竹节珊瑚一致。基于前人针对文石质冷水石珊瑚建立的钙化动力学模型,对方解石质竹节珊瑚的钙化过程进行模拟,结果表明:在钙化过程中,方解石质竹节珊瑚的碳酸酐酶(CA)活性显著低于文石质冷水石珊瑚,且其活性在珊瑚的生命历程中波动较大。根据同位素分馏通量平衡模型分析发现,竹节珊瑚骨骼的碳-氧同位素组成主要受控于溶解态CO2〔CO2(aq)〕羟基化和水合反应引起的动力学分馏,而跨细胞膜CO2(aq)通量导致的平衡同位素分馏对碳同位素分馏的贡献不超过50%。该认识有助于校正同位素生命效应对竹节珊瑚古海水温度重建结果的影响。

Abstract

The stable carbon and oxygen isotopes of the calcitic skeleton of cold-water bamboo corals can be used as a paleo-thermometer, but the imcomplete the understanding of their fractionation mechanisms limits the accuracy and range of its application in paleo-environmental reconstruction. We analyzed the stable carbon and oxygen isotope compositions of the calcitic skeleton of bamboo corals from the South China Sea, and found that their δ18O-δ13C slopes were similar to those of bamboo corals from the Pacific Ocean. Adapting a published kinetic calcification model of aragonitic cold-water scleractinian corals, we found that the carbonic anhydrase (CA) activity in calcitic bamboo corals was significantly lower than that in aragonitic cold-water scleractinian corals, and varied considerably throughout their entire lifespans. Based on the isotopic fractionation flux balance model, we found that the carbon and oxygen isotopes of bamboo coral skeletons were mainly affected by kinetic fractionations during aqueous CO2 hydration and hydroxylation, while equilibrium fractionation due to transcellular aqueous CO2 flux contributed no more than 50%. This result is helpful to correct for isotopic vital effects when reconstructing paleo-temperature.

关键词

冷水竹节珊瑚 / 南海 / 稳定碳-氧同位素 / 生物钙化机制 / 同位素分馏 / 动力学分馏模型 / 碳酸酐酶 / 古温度计

Key words

cold-water bamboo corals / the South China Sea / stable carbon and oxygen isotopes / biological calcification mechanism / isotope fractionation / kinetic fractionation model / carbonic anhydrase / paleo-thermometer

引用本文

导出引用
朱玉晗, 陈桑, 黄恩清, 等. 南海冷水竹节珊瑚碳-氧稳定同位素分馏机制[J]. 海洋学研究. 2026, 44(3): 91-101 https://doi.org/10.27049/j.cnki.1001-909X.2026027
Zhu Yuhan, Chen Sang, Huang Enqing, et al. Fractionation mechanism of stable carbon and oxygen isotopes in cold-water bamboo corals from the South China Sea[J]. Journal of Marine Sciences. 2026, 44(3): 91-101 https://doi.org/10.27049/j.cnki.1001-909X.2026027
中图分类号: Q959.133;P597   

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基金

国家重点研发计划(2021YFF0502500)
国家自然科学基金(42076061)
上海市科委基础研究特区计划(22TQ1400300)

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