甲烷流体活动与沉积物中碳、氮同位素组成响应——南海东北部海洋IV号地区研究

于晓果, 金肖兵, 姚旭莹, 龚建明

海洋学研究 ›› 2013, Vol. 31 ›› Issue (3) : 1-7.

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海洋学研究 ›› 2013, Vol. 31 ›› Issue (3) : 1-7.
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甲烷流体活动与沉积物中碳、氮同位素组成响应——南海东北部海洋IV号地区研究

  • 于晓果1,2, 金肖兵1,2, 姚旭莹1,2, 龚建明3
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The stable isotopic composition of sediments in methane fluid flowing area, Haiyang IV, the northern part of South China Sea

  • YU Xiao-guo1,2, JIN Xiao-bing1,2, YAO Xu-ying1,2, GONG Jian-ming3
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摘要

南海东沙群岛东北部海洋IV号地区GC16站重力柱状沉积物中的有机碳、总氮,以及自生碳酸盐岩矿物的无机碳同位素组成分析结果表明,甲烷流体活动区硫酸盐甲烷转换带(SMTZ—sulfate methane transition zone)是重要的生物地球化学界面,该带内沉积物中有机碳、氮与无机碳同位素组成变化明显。GC16站SMTZ上界面以下的沉积物中有机碳、氮同位素组成分别比其上的沉积物负偏1.4‰PDB和0.93‰,反映该带内甲烷缺氧氧化作用(AOM—anaerobic oxidation of methane)与氨氧化作用发育。无机碳同位素组成表明SMTZ界面之下沉积物中的自生碳酸盐岩矿物为以微生物为媒介的甲烷驱动成因,地质历史时期(至柱状沉积物底部沉积时期)曾发生过2次较强烈的CH4流体活动;目前该区甲烷流体活动较弱,甲烷流体影响深度与SMTZ上界面一致,未能到达海底。

Abstract

Sediments from the site GC16 of Haiyang IV, the South China Sea show anomalous values of δ13Corg, δ15N and δ13Cinorg. The sulfate methane transition zone (SMTZ) is a key biochemical interface in CH4 fluid flowing area. The values of δ13Corg and δ15N show obviously depleted in STMZ. Comparing with the date above the STMZ, depleted 1.4‰PDB and 0.93‰ respectively within the zone. The data of δ13Cinorg also identify the authigenic carbonates as microbially-mediated methane-derived precipitates. The 2 times of vigorous methane-rich fluid expulsion had occurred since the bottom sediments deposition of the core. The depth of methane fluid arriving coincident with the up limited of STMZ.

关键词

稳定位素组成 / SMTZ / AOM / 氨氧化作用

Key words

stable isotopic composition / SMTZ / AOM / ammonia oxidation

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于晓果, 金肖兵, 姚旭莹, 龚建明. 甲烷流体活动与沉积物中碳、氮同位素组成响应——南海东北部海洋IV号地区研究[J]. 海洋学研究. 2013, 31(3): 1-7
YU Xiao-guo, JIN Xiao-bing, YAO Xu-ying, GONG Jian-ming. The stable isotopic composition of sediments in methane fluid flowing area, Haiyang IV, the northern part of South China Sea[J]. Journal of Marine Sciences. 2013, 31(3): 1-7
中图分类号: P736.4   

参考文献

[1] REEBURGH W S. Oceanic methane biogeochemistry[J]. Chemical Reviews,2007,107(2):486-513.
[2] VAENTINE D L. Emerging topics in marine methane biogeochemistry[J]. Annu Rev: Mar Sci,2011,3:147-171.
[3] FRANCIS C A, BEMAN J M, KUYPERS M M. New processes and players in the nitrogen cycle: The microbial ecology of anaerobic and archaeal ammonia oxidation[J]. The ISME Journal,2007,1(1):19-27.
[4] SUESS E. RV SONNE cruise report SO177, Sino-German cooperative project, South China Sea continental margin: Geological methane budget and environmental effects of methane emissions and gashydrates[J/OL]. IFM-GEOMAR Reports,2005.http://oceanrep.geomar.de/1989/.
[5] SU Xin, CHEN Fang, WEI Shi-ping,et al. Preliminary study on the correlation between microbial abundance and methane concentration in sediments from cold seeps in the northern South China Sea[J]. Geo Science,2007,21(1):101-104.
苏新,陈芳,魏士平,等.南海北部冷泉区沉积物中微生物丰度与甲烷浓度变化关系的初步研究[J].现代地质,2007,21(1):101-104.
[6] JIANG Shao-yong, YANG Tao, XUE Zi-chen, et al. Chlorine and sulfate concentrations in pore waters from marine sediments in the north margin of the South China Sea and their implications for gas hydrate exploration[J]. Geo Science,2005,19(1):45-54.
蒋少涌,杨涛,薛紫晨,等.南海北部海区海底沉积物中孔隙水的Cl-和SO2-4浓度异常特征及其对天然气水合物的指示意义[J].现代地质,2005,19(1):45-54.
[7] WERNER R A, BRUCH B A, BRAND W A. ConFlo III: An interface for high precision δ13 C and δ15N analysis with an extended dynamic range[J]. Rapid Commun Mass Spectrom,1999,13(13):1 237-1 241.
[8] WANG Zheng, LIU Wei-guo, WEN Qi-bin. Measurement of nitrogen isotopic composition of soil samples by element analysis isotope mass spectrometry[J].Journal of Chinese Mass Spectrometry Society,2005,26(2):71-75.
王政,刘卫国,文启彬.土壤样品中氮同位素组成的元素分析仪-同位素质谱分析方法[J].质谱学报,2005,26(2):71-75.
[9] VALENTINE D L, KASTNER M, WARDLAW G D, et al. Biogeochemical investigations of marine methane seeps, Hydrate Ridge, Oregon[J]. J Geophys Res: Biogeosci,2005,110(G2):doi:10.1029/2005J Goooo25.
[10] MEYERS P A. Organic geochemical proxies of palaeoceanographic, palaeolimnologic and paleoclimatic processes[J]. Organic Geochemisry,1997,27(5/6):213-250.
[11] DEKAS A E, PORETSKY R S, ORPHAN V J. Deep-sea archaea fix and share nitrogen in methane-consuming microbial consortia[J]. Science,2009,326(5951):422-426.
[12] ROBINSON D. δ15N as an integrator of the nitrogen cycle trends[J]. Ecology & Evolution,2001,16(3):153-162.
[13] YU Xiao-guo, HAN Xi-qiu, LI Hong-liang, et al. Biomarkers and carbon isotope composition of anaerobic oxidation of methane in sediments and carbonates of northeastern part of Dongsha, South China Sea[J]. Acta Oceanologica Sinica,2008,30(3):77-84.
于晓果,韩喜球,李宏亮,等.南海东沙东北部甲烷缺氧氧化作用的生物标志化合物及其碳同位素组成[J].海洋学报,2008,30(3):77-84.
[14] PECKMANN J, THIEL V. Carbon cycling at ancient methane-seeps[J]. Chemical Geology,2004,205(3/4):443-467.

基金

国家自然科学基金项目资助(40576059,40976039);浙江省测试科技计划项目资助(2008F70047)

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