0 引言
1 研究区地质概况
2 样品选择与方法
3 实验结果
3.1 流体包裹体岩相学特征
图2 宝岛凹陷永乐10-6构造陵三段W1井、W2井、W3井和W4井典型流体包裹体显微荧光照片特征(a:W3井,4 061.6 m深度,紫外光下石英颗粒内发蓝色荧光的油包裹体;b:W3井,4 061.6 m深度,透射光下石英颗粒内发蓝色荧光的油包裹体及其同期盐水包裹体,为Fig.2a白框放大图像对应的透射光镜下视域;c:W1井,5 086.8 m深度,透射光下石英颗粒内的纯CH4气包裹体及其同期盐水包裹体;d:W4井,4 055 m深度,紫外光下石英颗粒内发蓝绿色荧光的油包裹体;e:W4井,4 055 m深度,透射光下石英颗粒内发蓝绿色荧光的油包裹体,为Fig.2d白框放大图像对应的透射光镜下视域;f:W3井,4 075.4 m深度,透射光下石英颗粒内的含CO2盐水包裹体及其同期的盐水包裹体;g:W2井,5 281.5 m深度,紫外光下石英颗粒内发黄色荧光的油包裹体;h:W2井,5 281.5 m深度,透射光下石英颗粒内发黄色荧光的油包裹体;i:W3井,4 122 m深度,透射光下的黑色沥青。图2a、2d和2g为紫外光下图像,图2b、2c、2e、2f、2h和2i为透射光下图像。) Fig.2 Characteristics of microscopic fluorescence photographs of typical fluid inclusions from Wells W1, W2, W3 and W4 in Member 3 of the Lingshui Formation, Yongle 10-6 Structure, Baodao Sag (a: Well W3, 4 061.6 m, blue fluorescent oil inclusions trapped in quartz grains under ultraviolet light; b: Well W3, 4 061.6 m, blue fluorescent oil inclusions as well as coeval aqueous inclusions trapped in quartz grains under transmitted light, as shown in white box in Fig.2a; c: Well W1, 5 086.8 m, single CH4-bearing gas inclusions as well as their coeval aqueous inclusions trapped in quartz grains under transmitted light; d: Well W4, 4 055 m, blue-green fluorescent oil inclusions trapped in quartz grains under ultraviolet light; e: Well W4, 4 055 m, blue-green fluorescent oil inclusions trapped in quartz grains under transmitted light, as shown in white box in Fig.2d; f: Well W3, 4 075.4 m, CO2-bearing aqueous inclusions as well as their coeval aqueous fluid inclusions arranged in quartz grains under transmitted light; g: Well W2, 5 281.5 m, yellow fluorescent oil inclusions arranged in quartz grains under ultraviolet light; h: Well W2, 5 281.5 m, yellow fluorescent oil inclusions trapped in quartz grains under transmitted light; i: Well W3, 4 122 m, bitumen observed under transmitted light. Figs. 2a, 2d, and 2g were taken under ultraviolet light, while Figs. 2b, 2c, 2e, 2f, 2h, and 2i were taken under transmitted light.) |
3.2 烃类包裹体荧光特征
图3 琼东南盆地宝岛凹陷南部断阶带永乐10-6构造典型油包裹体显微荧光光谱图Fig.3 Micro-fluorescence spectra of typical oil inclusions in the Yongle 10-6 Structure of the southern step-fault zone,Baodao Sag, Qiongdongnan Basin |
3.3 激光拉曼光谱特征
图5 宝岛凹陷南部断阶带陵三段石英颗粒内纯CH4气包裹体(a)、含CO2盐水包裹体(b)和沥青包裹体(c)激光拉曼光谱图Fig.5 Laser Raman spectra of single CH4 gas-phase inclusions (a), CO2-bearing gas-phase inclusions (b),and bitumen inclusions within quartz grains (c) from Member 3 of the Lingshui Formation, southern step-fault zone, Baodao Sag |
3.4 流体包裹体均一温度
表1 永乐10-6构造陵三段流体包裹体均一温度统计结果Tab.1 Statistical results of homogenization temperature of fluid inclusions from Member 3 of the Lingshui Formation, Yongle 10-6 Structure |
| 井名 | 深度/m | 层位 | 均一温度/℃ | ||||
|---|---|---|---|---|---|---|---|
| 油包裹体 | 与油包裹体伴生 的盐水包裹体 | 与纯CH4气包裹体 伴生的盐水包裹体 | 含CO2盐水包 裹体 | 与含CO2盐水包裹体 伴生的盐水包裹体 | |||
| W1 | 5 067.2~5 288.2 | LS3 | 107.8~169.2 | 36.4~38.2 | 171.1~184.7 | ||
| W2 | 5 134.3~5 209.3 | LS3 | 52.8~87.2 | 105.6~121.9 | 107.2~188.1 | 32.7~35.2 | 157.5~160.2 |
| W3 | 4 020.1~4 122.0 | LS3 | 80.4~89.6 | 90.6~169.9 | 87.2~184.1 | 21.4~30.2 | 126.1~180.8 |
| W4 | 4 021.0~4 082.1 | LS3 | 85.2~183.2 | 29.8~34.4 | 85.8~168.1 | ||