基于海水环境和气象参数经验公式估算的东海海-气CO2通量

李熠, 何海伦, 陈大可

海洋学研究 ›› 2012, Vol. 30 ›› Issue (3) : 30-40.

PDF(3175 KB)
PDF(3175 KB)
海洋学研究 ›› 2012, Vol. 30 ›› Issue (3) : 30-40.

基于海水环境和气象参数经验公式估算的东海海-气CO2通量

  • 李熠1, 何海伦1,2, 陈大可*1
作者信息 +

Air-sea CO2 flux in the East China Sea estimated by empirical formula based on the parameters of

  • LI Yi1, HE Hai-lun1,2, CHEN Da-ke*1
Author information +
文章历史 +

摘要

使用 World Ocean Altas 2009提供的气候态月平均温度、盐度和磷酸盐浓度资料,以及Globalview和NCEP的大气资料, 借助较为可靠的经验公式,估算了东海海表CO2分压(pCO2 )和海-气CO2通量的平均分布特征和季节变化。结果表明,pCO2的空间分布形态四季大体相同, 但其强度随季节变化, 春、冬季低,夏、秋季高。CO2通量在东海陆架区为汇,汇的强度从NW向SE逐渐减弱;在黑潮区为源,强度从SW向NE逐渐减弱。东海整体于春、冬季为CO2的汇,夏、秋季为CO2的源。进一步分析东海pCO2和CO2通量季节变化的主要影响因子表明,东海海表pCO2变化主要受温度控制,而在陆架区,盐度和磷酸盐的作用不可忽略。东海整体CO2通量变化在4至10月由风速主导,11月至翌年3月由海表pCO2控制;陆架区CO2通量的季节变化主要由风速决定;黑潮区CO2通量的变化在夏季由风速主导,秋季由风速和pCO2共同影响。

Abstract

Using the empirical formula of TSUNOGAI et al, a preliminary study was made on the climatological distribution and seasonal variation of the sea surface pCO2 and air-sea CO2 flux in the East China Sea,and the influence of sea surface temperature, salinity, phosphate concentration and wind speed. The formula was based on environmental parameters ( sea surface temperature, salinity and phosphate concentration). The data used were from WOA09 ( monthly mean climatological sea surface temperature, salinity and phosphate concentration) ,Globalview ( atmospheric pCO2 ) and NCEP ( monthly mean wind speed). The spatial distribution of the calculated pCO2 maintains a gradually increasing trend from the northwest to the southeast while its magnitude varies significantly with seasons, lower in spring and winter, higher in summer and autumn. Space-time pattern of the CO2 flux varies obviously, the continental shelf region as a whole is the convergence of CO2 from atmosphere, while the Kuroshio region is the source. The convergence intensity gradually weakens from the northwest to the southeast and that of source strengthens from the north to the south. The East China Sea uptake CO2 from atmosphere in spring and winter while release CO2 to atmosphere in summer and autumn.
Analysis of seasonal change of the sea surface pCO2 in the East China Sea shows that SST is its main controlling factor. They change in the same phase, reache the maximum in summer and minimum in winter. In the Kuroshio area, salinity and phosphate concentration remains stable all the year round, their seasonal variations could be neglected and the variation of pCO2 is completely controlled by temperature. In the continental shelf area, the changes of salinity and phosphate concentration are contrary to that of temperature,but the magnitude is relatively low. The seasonal change of pCO2 is still controlled by SST in most of the months except June,July and December,when the role of salinity and phosphate concentration tops that of SST.
For the East China Sea as a whole, the CO2 flux changes with the wind speed from April to October, indicating that the wind speed is the leading role in the air-sea CO2 exchange. During this period, the wind speed changes significantly due to monsoon conversion, which has great impacts on the CO2 flux. From November to March, the CO2 flux changes with sea surface pCO2, when the wind speed remains high all along and pCO2 varies significantly. In the continental shelf area, the surface pCO2 remains lower than the atmosphere pressure all along,and the CO2 flux is smaller than zero, its magnitude is closely related to the wing speed,and obviously high in winter except for a relatively high value in July associated with the strengthening of summer monsoon. The CO2 flux in the Kuroshio area is year-round positive and has a maximum in June-July and October-November respectively. The extreme value in June-July is closely related to summer monsoon enhancement,while that in October-November to the start of the winter monsoon and wind speed enhancement. It should be noted that though the wind speed is strong in winter, the CO2 flux is not great because of comparatively low surface pCO2. The variation of CO2 flux in Kuroshio area is controlled by both wind speed and surface pCO2.

关键词

海表CO2分压 / 海-气CO2通量 / 东海

Key words

partial pressure of CO2 / air-sea CO2 flux / the East China Sea

引用本文

导出引用
李熠, 何海伦, 陈大可. 基于海水环境和气象参数经验公式估算的东海海-气CO2通量[J]. 海洋学研究. 2012, 30(3): 30-40
LI Yi, HE Hai-lun, CHEN Da-ke. Air-sea CO2 flux in the East China Sea estimated by empirical formula based on the parameters of[J]. Journal of Marine Sciences. 2012, 30(3): 30-40

参考文献

[1] SOLOMON S, QIN Da-he, MANNING M, et al.Climate change 2007: The physical science basis, contribution of working group I to the fourth assessment report of the intergovernmental panel on climate change [M]. Cambridge and New York: Cambridge University Press, 2007.
[2] TAKAHASHI T,SUTHERLAND S C,WANNINKHOF R,et al.Climatological mean and decadal change in surface ocean pCO2,and net sea-air CO2 flux over the global oceans[J]. Deep Sea Research Part II, 2009, 56(8) :554-577.
[3] WATSON R T,NOBLE I R.Carbon and the science-policy nexus: The Kyoto challenge[C]// STEFFEN W, JAGER J,CAR-SON D, et al. Challenges of a changing earth. Proceedings of the
global change open science conference, Amsterdam,The Nether lands, 10-13 July 2001. July 2001. Berlin: Springer, 2001:57-64.
[4] SVERDRUP H, JOHNSON M w, FLEMING R H. The oceans: Their physics, chemistry and general biology[M]. NJ: Prentice Hall, 1942.
[5] TSUNOGAI S,WATANABES, SATO T.Is there a“continental shelf pump” for the absorption of atmospheric CO2[J]? Tellus, 1999, 51B(3):701-712.
[6] THOMAT H,BOZEC Y, DE BAAR H J W. The carbon budget of the North Sea[J]. Biogeosciences, 2005 2:87-96.
[7] THOMAS H, SCHNEIDER B.The seasonal cycle of carbon dioxide in Baltic Sea surface waters[J]. Journal of Marine Systems, 1999, 22(1) :53-67.
[8] CAI Wei-jun, CHEN Li-qi,CHEN Bao-shan, et al.Decrease in the CO2 uptake capacity in an ice free Arctic Ocean Basin[J]. Science, 2010, 329(5991) :556-559.
[9] CAI Wei jun. Estuarine and coastal ocean carbon paradox: CO2 sinks or sites of terrestrial carbon incineration[J]? Annual Review of Marine Science, 2011 , 3: 123-145.
[10] CHEN CT A,BORGES A V.Reconciling opposing views on carbon cycling in the coastal ocean: Continental shelves as sinks and near shore ecosystems as sources of atmospheric CO2[J]. Deep Sea Research Part II, 2008, 56(8) :578-590.
[11] SONG Jin-ming,XU Yong-fu,HU Wei-ping,et al.Biogeochemistry of carbon in China seas and lakes [M]. Beijing: Science Press, 2008.
宋金明, 徐永福, 胡维平,等.中国近海与湖泊碳的生物地球化学[M].北京:科学出版社, 2008.
[12] DAI Min-han, ZHAI Wei-dong, LU Zhong-ming, et al.Regional studies of carbon cycles in China: Progress and perspectives[J]. Advances in Earth Science , 2004, 19(1):120-130.
戴民汉, 翟惟东, 鲁中明,等.中国区域碳循环研究进展与展望[J].地球科学进展, 2004, 19(1):120-130.
[13] SUN Yun-ming, Song Jin-ming.Advances in biogeochemical process research on marine carbon cycles in China(1998-2002)[J]. Advances in Marine Science, 2002 , 20(3):110-118.
孙云明, 宋金明.中国海洋碳循环生物地球化学过程研究的主要进展(1998-2002)[J]. 海洋科学进展, 2002, 20(3):110-118.
[14] HU Dun-xin, YANG Zuo-sheng.Key processes of the ocean flux in the East China Sea [M]. Beijing: Ocean Press, 2001.
胡敦欣, 杨作升.东海海洋通量关键过程[M].北京:海洋出版社, 2001.
[15] W ANNINKHOF R.Relationship between wind and gas exchange over the ocean[J]. Journal of Geophysical Research, 1992, 97(5) :7373-7 382.
[16] WANNINKHOF R,MCGILLS W R.A cubic relationship between air-sea CO2 exchange and wind speed[J]. Geophysical Research Letters, 1999, 26( 13):1 889-1 892.
[17] W ANNINKHOF R, ASHER W E,HO DT,et al. Advances in quantifying air-sea gas exchange and environmental forcing[J]. Annual Review of Marine Science, 2009, 1(1) :213-244.
[18] HO DT,WANNINKHOF R, SCHLOSSER P, et al. Toward a universal relationship between wind speed and gas exchange: Gas transfer velocities measured with 3 He/SF6 during the Southern Ocean gas exchange experiment[J]. Journal of Geophysical Research, 2011, 116,C00F04, doi:10.1029/2010JC006854.
[19] GLOVER M D, FREW N M,MCCUE SJ,et al.A multiyear time series of global gas transfer velocity from the TOPEX dual frequency,normalized radar backscatter algorithm[C]// DONELAN M A,DRENNAN W M,SALTZMAN E S, et al. Gas transfer at water surfaces. Washington DC: AGU, 2002.
[20] WOOLF D K.Parametrization of gas transfer velocitiesand sea-state-dependent wave breaking[J]. Tellus, 2005, 57B(2):87-94.
[21] FANGOHR S, WOOLF D K.Application of new parameterizations of gas transfer velocity and their impact on global and regional marine CO2 budgets[J]. Journal of Marine Systems, 2007 , 66(1):195-203.
[22] WEISS R F, PRICE B A.Nitrous oxide solubility in water and seawater[J]. Marine Chemistry, 1980, 8(4) :347-359.
[23] CHOU W C, GONG G C, SHEU D D, et al. Surface distributions of carbon chemistry parameters s in the East China Sea in summer2007[J]. Journal of Geophysical Research, 2009, 114:JC07026,doi: 10.1029/2008JC005128.
[24] ZHANG Yuan-hui, HUANG Zi-qiang,MA Liming, et al.Car-bon dioxide in surface water and its flux in East China Sea[J]. Journal of Oceanography in Taiwan Strait, 1997, 16(1) :37-42.
张远辉,黄自强,马黎明, 等.东海表层水二氧化碳及其海气通量[J]. 台湾海峡, 1997, 16(1) :37-42.
[25] ZHANG Long-jun.The study on the CO2 flux at the sea-atmos-phere interface over the East China Sea [D]. Qingdao: Ocean University of China, 2003.
张龙军. 东海海-气界面CO2通量研究[D].青岛:中国海洋大学, 2003.
[26] JI Lei, CUI He,XIN Shu-ping, et al.Characters of pCO2 and CO2 flux in the East China Sea in autumn[J]. Chinese Journal of Oceanology and Limnology , 2003, 21(2) : 180-186.
[27] CHANG Lo-ping.Surface distributions of carbon chemistry parameters in the East China Sea in winter ( January 2008)[D]. Keelung: National Taiwan Ocean University, 2009.
张络萍.东海冬季(2008年1月)碳化学参数之分布特征[D].基隆:国立台湾海洋大学, 2009.

基金

国家海洋局环保司资助项目; 国家自然科学基金-重大研究计划重点支持项目(91128204); 海洋公益性行业科研专项经费项目(201105018); 国家海洋局第二海洋研究所基本科研业务费专项资金项目(JG1027)

PDF(3175 KB)

Accesses

Citation

Detail

段落导航
相关文章

/