海洋学研究 ›› 2018, Vol. 36 ›› Issue (1): 58-65.DOI: 10.3969/j.issn.1001-909X.2018.01.006

• 研究论文 • 上一篇    下一篇

溢油污染物在海底沉积物中的识别与垂向迁移——大连湾海底沉积物研究

于晓果1,2, 杨海丽1,2, 刘星3, 雷吉江1,2, 林忠胜3, 姚子伟2, 章伟艳1,2, 姚旭莹1,2, 金肖兵1,2   

  1. 1.国家海洋局 海底科学重点实验室,浙江 杭州 310012;
    2.国家海洋局 第二海洋研究所,浙江 杭州 310012;
    3.国家海洋环境监测中心,辽宁 大连 116023
  • 收稿日期:2017-07-13 修回日期:2017-12-27 出版日期:2018-03-15 发布日期:2022-11-21
  • 作者简介:于晓果(1964-),女,山东潍坊市人,研究员,主要从事有机地球化学与同位素地球化学研究。E-mail:yuxiaoguo@sio.org.cn
  • 基金资助:
    国家海洋公益性行业科研专项项目资助(201205012-11)

Split oil identified and vertical migration in sediment of seabed: Case in Dalian Bay

YU Xiao-guo1,2, YANG Hai-li1,2, LIU Xing3, LEI Ji-jiang1,2, LIN Zhong-sheng3, YAO Zi-wei3, ZHANG Wei-yan1,2, YAO Xu-ying1,2, JIN Xiao-bing1,2   

  1. 1. Key Laboratory of Submarine Geosciences,SOA, Hangzhou 310012, China;
    2. Second Institute of Oceanography, SOA,Hangzhou 310012, China;
    3. National Marine Environmental Monitoring Center, Dalian 116023,China
  • Received:2017-07-13 Revised:2017-12-27 Online:2018-03-15 Published:2022-11-21

摘要: 沉积物插管短柱样品于2013年4月采自大连湾2010年“7·16”溢油事故污染区,BQ050站与BQ007站分别位于生物分散剂和化学分散剂喷洒区。沉积物的可溶有机质含量(沥青A)、有机碳同位素组成(δ13Corg)和210Pb比活度分析结果表明:喷洒生物分散剂的重污染区(BQ050站),沉积物中TOC含量为0.58%~1.51%,平均为1.15%;δ13Corg值为-22.2‰~-20.5‰PDB,平均为-21.74‰PDB;沥青A含量为0.061 5%~0.566 4%,平均为0.174 9%;沥青A/TOC比值为7.0%~34.8%,平均为14.13%;210Pbex比活度存在异常峰值分布,垂向分布特征与沥青A相似;2~16 cm段沉积物的可溶有机质具有明显的外来输入特征。喷洒化学分散剂的较轻污染区(BQ007站),沉积物中TOC含量为0.61%~1.14%,平均为0.87%,除8~14 cm层段外,比BQ050站略低;但沥青A含量与沥青A/TOC比值明显低于前者;δ13Corg值较BQ050站轻;210Pbex比活度随柱样深度呈指数衰减,对数相关;外来有机质输入量较低。截至2013年4月,BQ050站溢油污染物在海底下16 cm深度处有特征信号,溢油污染物沥青A 组分垂向迁移距离约为15 cm。

关键词: 溢油, 沉积物, 沥青A, δ13Corg, 210Pbex

Abstract: Two core sediment samples collected in the area of 16th July 2010 split oil accident by box crab during April 2013. The biological dispersant were used during the split treatment in heavy pollution area. Site BQ050 and Site BQ007 located in the area where biological dispersant and chemical dispersant were used, respectively. The TOC content, soluble organic content (asphalt A), δ13Corg value and 210Pbex of sediments were analyzed for identifying the contaminated organic matters. The sediments of Site BQ050 have higher organic matter content (TOC: 0.58%~1.51%, mean: 1.15%; asphalt A: 0.061 5%~0.566 4%, mean: 0.174 9%, up to 0.566 4% in depth 10~12 cm), heavier δ13Corg value(-22.2‰~-20.5‰PDB, mean: -21.74‰PDB), and higher asphalt A/TOC ratio (7.0%~34.8%, mean: 14.13%) indicating that the organic matter characterized by exotic. Meanwhile, the δ13Corg values of sediments are similar, which shows the same organic input in the depth from 2 cm to 16 cm. The 210Pbex of sediments has the similar distribution to the asphalt A. The sediments of Site BQ007 have much lower asphalt A content and asphalt A/TOC ratio compared to the sediments of Site BQ050, and the 210Pbex distribution is normal. The content of 210Pbex decreasing with depth shows the logarithmic correlation. The exotic organic matter is low in the Site BQ007. The split oil(characterized by asphalt A)has been migrated to about depth of 16 cm in the Site BQ050 until April 2013.

Key words: split oil accident, sediment, asphalt A, δ13Corg value, 210Pbex

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