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Marine gas hydrate deposits are significant temporal reservoirs for hydrocarbons migrating from deep sources. This is crucial to our understanding of ocean carbon cycling. The cold seep, a geological process regarding gas leakage from deep or shallow sources, is usually linked with gas hydrate decomposition. In this thesis, we reviewed the latest applications of in situ monitoring and detecting methods regarding the leakage plumes, migration pathways, and seafloor geomorphologies associated with gas hydrate and cold seep systems, primarily including vessel-and land-based gas plume measurements, surface ocean-lower atmosphere hydrocarbon emission detections, seafloor visualization techniques, and in situ observation networks. The integrated applications of these in situ observation methods provide a nuanced view of the temporal and spatial variability of hydrate and cold seep systems, facilitate understanding of the fate of hydrocarbons, and expand our knowledge of cold-seep biota in a watery desert.

 The temporal and spatial change characters of coastline and tidal flat in the islands with different principle functions in the Zhoushan Archipelago were analyzed, using a coastal remote sensing monitoring dataset with 30 m spatial resolutions at annual interval from 1986 to 2017. The results suggested that the coastlines in Zhoushan Archipelago advanced toward the sea, with many water areas(152 km2) and tidal flats(18 km2) reclaimed into lands and the government policies were the main driven factors. The change characters were various among the islands with different principle functions. In particular, the land reclamation was significant in the islands with the principle functions of comprehensive development, coastal industry, coastal tourism, and harbor and logistics, accounting for 96% of the archipelagos new lands. The land reclamation was slight in the islands with marine science and education and scientific fishery functions, accounting for 4% of the archipelagos total new lands. Meanwhile, the coast was stable and well protected in the islands with ecological conversation and clean energy functions. The results could provide scientific basis for coastal zones ecological protection and restoration projects, as well as the marine principle functional zoning.

The monitoring of carbon flux dynamics and assessment of carbon sink functions of island forest ecosystems are rarely reported due to their special geographical location and few data sources. In this study, the forest ecosystem of the Nanji Island was used as the research object, the carbon sink potential of island forests and their driving factors were assessed. Based on eddy correlation techniques, the temporal variation characteristics and driving factors of net ecosystem productivity (NEP), gross primary productivity (GPP), and ecosystem respiration (Reco) from 2020 to 2021 were explored. Results showed that the forest ecosystem of Nanji Island was carbon sink. Net CO₂ uptake in 2020 and 2021 were 516 g C·m^-2·a^-1 and 598 g C·m^-2·a^-1, Reco were 1 037 g C·m^-2·a^-1 and 1 646 g C·m^-2·a^-1, and GPP were 1 552 g C·m^-2·a^-1 and 2 244 g C·m^-2·a^-1, respectively. Total solar radiation (Rg), photosynthetically active radiation (PAR), net radiation (Rn) and sensible heat (H) were significantly and positively correlated with NEP and GPP (p≤0.001); air temperature (Tair) and soil temperature (Tsoil) were significantly and positively correlated with Reco(p≤0.001). The photosynthesis time of Nanji Island forest was longer than the carbon sink time on the daily scale. When Tair reached 10.05-27.76 ℃ and PAR reached 110.47-429.44 μmol·m^-2·s^-1, the photosynthesis intensity of island forest was higher than that of ecosystem respiration, which showed CO₂ absorption. The monitoring and assessment of carbon fluxes in the forest ecosystems of Nanji Island will provide an important theoretical support for the establishment of a dynamic monitoring and assessment management system for blue carbon in China.

Sea surface temperature (SST) is the critical factor for depicting the marine thermal distribution. Daily global SST data sets support the typhoon elaborated monitoring and other marine disasters forecast. SST products retrieved by the visible infrared radiometers and mediumresolution imagers have high spatial resolution, while the SST products retrieved by infrared remote sensing are affected by clouds, fog and haze, and therefore a large areas under the clouds are lack of value. SST products retrieved by the microwave radiometer have low spatial resolution, while the microwave could penetrate the cloud layer to achieve all-weather sea surface observation. The data interpolation empirical orthogonal function method (DINEOF) was used to reconstructed the global SST products, and FY-3 (Fengyun 3) SST data sets were applied in this study, which included the SST data sets from the FY-3B/FY-3C Visible and Infra-Red Radiometer, FY-3D Medium Resolution Spectral Imager and FY-3D Micro-Wave Radiation Imager. Accuracy of the reconstructed data sets was verified using OISST measurements to demonstrate the validity and reliability of the DINEOF method. The results show that DINEOF reconstructed sea surface temperature (DSST) data are validated reliable. Root mean square error of the original data is ranging from 0.59 ℃ to 0.70 ℃, while the reconstructed data is relatively stable, ranging from 0.10 ℃ to 0.34 ℃. Correlation coefficient obvious raises from 0.33-0.48 to 0.78-0.98. Multi-sensors reconstructed SST products is continuous and credible in spatial distribution and monitor the variation of warm pool from spring to winter. Addition of FY-3D microwave SST products has significantly improved the spatial continuous distribution and temporal resolution of reconstructed SST.

With the advancement of observation technology and the improvement of ocean numerical simulation capabilities, some stable subsurface coherent vortices have been widely observed in the ocean, which far from the formation source area. These vortices possess distinctive dynamic characteristics, such as a low potential vorticity center, lens-like structure of isopycnals, weak stratification, and anomalous temperature, salinity, or other tracer properties compared to the surrounding water mass. Their core flow is relatively stronger. These subsurface coherent vortices significantly impact ocean water mass transport, thermohaline circulation and marine biological environment. This paper comprehensively summarizes researches on subsurface coherent vortices in the ocean, including their structure, hydrological characteristics, identifying methods, global distribution, dynamic mechanisms and their important effects on ocean environment. Furthermore, the research perspectives are discussed, such as the difficulties in the research and the issues that need to be solved to comprehensively understand subsurface coherent vortices in the ocean.

Climate reconstructions for the last millennium are essential for understanding climate change and will provide an important basis for predicting future climate change. However, there are spatial differences in monsoonal precipitation, and the hydrothermal configurations of two important characteristic periods of the past millennium, the Medieval Warm Period and the Little Ice Age, are highly controversial, especially in southern China. Therefore, the Core BBG-02 taken from the northeastern Beibu Gulf were analyzed for chronology, grain size, major elements and trace elements to understand the physical source of the Core BBG-02 and the climate and environmental changes in its source area. The analysis of chondrite-normalized distribution patterns of rare earth element and geochemical indicators reveal that the Red River may be the main source of the Core BBG-02, and the changes in geochemical indicators of the core reflect changes in the intensity of Indian Summer Monsoon. The results indicate that the climate was warm and humid during the Medieval Warm Period and cold and arid during the Little Ice Age, which is consistent with the results of previous studies on the variation of Indian Summer Monsoon and precipitation. The variation of solar radiation intensity is the essential reason of the variation of Indian Summer Monsoon, which is also influenced by ENSO activity and Indian Ocean Dipole.

Wave is an important factor to shape the dynamic geomorphology of the open tidal flat, but researches on tidal-flat wave characteristics are still limited. Taking Nanhui tidal flats in the Changjiang Estuary as an example, the wave characteristic parameters and wave spectrum parameters were obtained by inverting flow-velocity and water-pressure data from the Acoustic Doppler Velocimeters (ADVs) at some fixed platforms, and their changes over tidal cycles and associated influence mechanisms were discussed. The results show that both normal wave direction and prominent wave direction at three stations of Nanhui tidal flats are mainly southeast during the observation period, with long-period swells dominating. The effective wave height of the three stations is positively correlated with the water depth, but the fitting coefficients of each station are different over flood and ebb periods. Wave orbital velocities are obviously modulated by the shallow water effect and the flow directions, and their maximum values usually occur at the early flooding stage, while minimum values can be observed to occur during the current transition periods. The wave energy spectrum during ebb tides is featured by the bimodal pattern because of high influence by tidal levels and coastal topography, and the peak energy is continuously attenuated and gradually dispersed with the concurrent shift of peak frequencies.

Since a diagram depicting "The Great Ocean Conveyor" was first appeared as a logo by Wally Broecker in 1987, how the warmed upper ocean circulation ran through the Indonesian Seas with their complex coastline geometry and narrow passages, known as the Indonesian through-flow, becomes one of the difficult settings in boundary conditions of climate change model. With strong nonlinear effect, a shallow narrow passage forms vertical mixed hotspots on the one hand, and on other hand, it becomes a self-adapted low-pass filter if the tidal resonance units are introduced. Qiongzhou Strait, a sufficient sediment supply and shallow narrow passage for the northern shelf of the South China Sea, is reported with strong tidal current and westward through-flow. And its tidal channel and tidal deltas are maintained by the tidal resonance units introduced themself. Strong disturbances such as typhoon and cold wave can cause storm jet flow through the strait, triggering different high nutrition, algal bloom and hypoxia events over the adjacent Beibu Gulf. Qiongzhou Strait seems to be a noteworthy case of studying how the self-adapted low-pass filter introduced and whether human activities can affect the through-flow on the shallow narrow passages.

There is strong tide in the Changjiang (Yangtze River) Estuary and its adjacent area. Except for the coast area, there is a lack of longterm tide level and tidal current data in the offshore area. Long time series of water level observation data was used in this study, and the results reveal that the tidal type in the Changjiang Estuary is a regular semidiurnal tide, with a significant shallow water division in the nearshore area; the M2 division is the most significant semidiurnal tide, and the amplitude tends to increase from the open sea in the east to the shallow water or island group at the mouth of Hangzhou Bay in the west. The M2 tidal current is the most significant semidiurnal tidal current, and the rotating tide is the most significant semidiurnal tide. The two stations to the south of the Changjiang mouth are rotating counterclockwise, while the stations to the east of the mouth are rotating clockwise. The vertical structure of the tide has significant spatial differences, the ellipticity of the M2 tidal current is mostly negative, the ellipticity of the M2 tidal current, the direction and the arrival time of maximum velocity all vary significantly with depth.

Artificial intelligence in oceanography has demonstrated a great potential with the explosive growth of ocean observation data and numerical model products. This article first reviews the history of ocean big data development, and then introduces in detail the current status of artificial intelligence in oceanography applications including identifying ocean phenomenon, forecasting ocean variables and phenomenon, estimating dynamic parameters, correcting forecast errors, and solving dynamic equations. Specifically, this article elaborates the research on the intelligent identification of ocean eddies, internal waves and sea ice, the intelligent prediction of sea surface temperatures, El Ni?o-Southern Oscillation, storm surges, waves and currents, the intelligent estimation of ocean turbulence parameterization for numerical models, and the intelligent correction of waves and current forecast errors. In addition, it discusses the recent progress of applying physical mechanism fusion and Fourier neural operator for solving ocean dynamic equations. This article is based on the current status of artificial intelligence in oceanography and aims to provide a comprehensive demonstration of the advantages and potential of applying artificial intelligence methods in the field of oceanography. With the two emerging research hotspots: digital twin oceans and artificial intelligence large models, the future development direction of artificial intelligence provides enlightenment and reference for interested scientists and researchers.

Mangroves, coastal salt marshes and seagrass beds, as the typical coastal blue carbon ecosystems, have been widely recognized for their remarkable capacity in carbon storage. Vegetation carbon pool and sediment (or soil) carbon pool were considered to be the major carbon pools within the coastal blue ecosystems and their variations determined the overall carbon sequestration of the ecosystems. From a perspective of carbon pool interactions, this study summarized the previous research work based on literature review, including the interactions within various vegetation carbon pools and within various sediment carbon pools, as well as the interactions between vegetation and sediment carbon pools. Interspecific competition, allochthonous carbon input and biogeomorphology were found to be the key to understand the carbon pool interactions. Finally, a perspective on the current state-of-the-art of blue carbon pool study is offered, with challenges and suggestions for future directions.

The river-estuary-coastal ocean continuum (referred to as the continuum hereinafter) is a transition zone connecting lands and oceans. The carbon budgets in the continuum are dynamic and uncertain components in global carbon budgets. This complex landocean interactive ecosystem can absorb atmospheric CO2 through photosynthesis and dissolution of CO2. Also, the carbon fixed by photosynthesis or chemical weathering in land and watershed can be transported horizontally to the shelf waters and open oceans. In this paper, the progress of carbon cycles in the continuum is reviewed by taking the famous Chesapeake Bay and Changjiang Estuary-East China Sea continuum as typical examples. It is concluded that systematic observation characterized with land-sea coordination, sea-space integration, point-line combination, should be combined with physicalecological numerical simulation to reveal the multiple time-space scale processes. The strategy is generally operable, and the historical retrospective of results is also achievable. Thus, it can be used to clarify the evolution of carbon exchange along the river-estuary-coastal ocean continuum and their influences on carbon budgets under the combined pressures of climate change and anthropogenic activities.

In order to explore the distribution, formation mechanism and motion law of eddy around Kuroshio in East China Sea, firstly, the eddy distribution around the Kuroshio in the East China Sea during the past 27 years was analyzed by using the mesoscale eddy data set of the AVISO(Archiving, Validation and Interpretation of Satellite Oceanographic Data). The results show that there are 650 eddies generated in the meander of the Kuroshio, and 271 eddies in the middle part of the Kuroshio. The diameters of the most these eddies were between 100 to 150 km, and the amplitudes were between 2 to 6 cm. Secondly, the motion path and eddy motion process of the Kuroshio in the East China Sea are also analyzed. The results show these the cyclonic eddies are easy to be generated in the inner side of the Kuroshio cyclonic bend, with a long path. For example, at the cyclone bend of the Kuroshio axis in the northeast of Taiwan, the average length of the path was 87.6 km. Otherwise, when these anticyclonic eddies are generated, these eddies usually are wandered. In the middle part of the Kuroshio, the eddy showed the polar symmetric distribution characteristics of these cyclonic eddies in the west side of the Kuroshio main axis and these anticyclonic eddies in the east side of the Kuroshio main axis. Both types of eddies moved northeastward along the Kuroshio main axis. Finally, combined with reanalysis data sets of ocean current and sea surface height, the eddy motion law and generation mechanism were discussed. It is concluded that these eddies generation at the curve of the Kuroshio are related to the separation of the boundary layer of the Kuroshio fluid. The Kuroshio countercurrent from the south of Yanmei Island to the west of Okinawa Island played a key role in the polar symmetric distribution of these eddies in the middle part of the Kuroshio. These eddies usually experience three stages of growth, maturation and decay in the process of movement.

Taking Beibu Gulf, South China Sea as a case, the occurrence, source, and ecological risks of 12 organophosphate esters (OPEs) were investigated in 34 surface sediment samples. The Σ12OPEs in the sediments ranged from <LOQ to 35.1 ng·g^-1. Triphenyl phosphate (TPHP), tri-n-butyl phosphate (TNBP), tris (2-chloro-propyl) phosphate (TCIPP) and tris (2-chloroethyl) phosphate (TCEP) were the dominant OPEs in the surface sediments. Generally, the total mass fraction of OPEs detected in sediments from the offshore was higher than that in the near shore, and the mass fraction for major OPEs were also different between the above two areas. On the one hand, the main reason might be related to their physiochemical properties. TPHP and TNBP compounds with higher lipophilicity might be more likely to accumulate in the sediments. On the other hand, it might be related to the source. For example, the OPEs detected in the offshore might be related to the oil exploitation and transportation, submarine optical cable and oil pipeline laying, shipping activities and the transportation of circulation in Beibu Gulf, while the discharge of life and industrial sewage as well as marine aquaculture might be the major sources for OPEs detected in the inshore area. Risk assessment revealed that most individual OPE could pose low ecological risks, but medium ecological risks of TPHP and the mixture of OPEs on aquatic organisms were found, which requires more attention. Therefore, the OPEs pollution situation in Beibu Gulf needs to be paid attention to, especially the pollution emission and control TCIPP and TCEP from inshore area, as well as TPHP and TNBP from offshore area, so as to reduce OPEs pollution from the source.

Aiming at the problems of difficulty in verifying the accuracy of the interpolation model of single-beam bathymetric data, a method based on high-precision UAV data to verify the accuracy of the interpolation model was proposed by using the intertidal tidal law. At low tide, UAV photogrammetry was used to construct a high-precision digital surface model (DSM) of the intertidal zone, and at high tide, the single-beam bathymetry data was obtained and the three-dimensional coordinates of the intertidal topographic points were calculated by combining the global navigation satellite system (GNSS) technology, and constructed an intertidal digital elevation model (DEM) by using the following 4 interpolation methods: Kriging, inverse distance weight, completely regularized spline and natural neighborhood interpolation method. Based on UAV data, the accuracy analysis of intertidal zone DEM was carried out. The results show that: (1) PPK technology-assisted UAV photogrammetry can construct high-precision intertidal zone DSM. (2) In the intertidal zone, UAV data can be used as an evaluation criterion for the accuracy of single-beam bathymetry data. (3) When the seabed topography is relatively flat, the completely regularized spline method has higher accuracy than the other three methods, and the coarse difference rate is 12.5%.

The Landsat TM/OLI remote sensing images from 1973 to 2018 were obtained as the data source by using the remote sensing and GIS technology. Based on the geographical background information, the spatial and temporal evolutions of the coastline in the Pearl River Delta region over 45 years were analyzed. The results show that the Pearl River Delta changed significantly, a large number of muddy coast changed into urban industrial coast and port coast. The artificialization index of Pearl River Delta coastline was rising, the types of coastline were developed in a diversified direction, the total length and fractal dimension of shoreline were increasing continuously, the main factors of increase shoreline length and fractal dimension were port construction, coastal industrial zone and reclamation.The evolution of the coastline had obvious regional characteristics, and the regions with large changes were mainly concentrated in Shenzhen Mirs Bay, Guangzhou Nansha and Zhuhai Doumen. From the perspective of the main structure of shoreline, each region presented different type changing tendency, substituted the natural shoreline, the industrial and port shorelines became the main type in each region. The intensity of development and utilization was increasing in various regions, among which the intensity of development in Shenzhen was growing the fastest. Social activities and location policies were the main driving factors for the evolution of shoreline.

Electrochemical methods are the main methods for measuring seawater pH. The self-developed electrochemical pH sensor is based on iridium metal and its oxide electrode, a method for its calibration and data correction in seawater environment was established and applied for in-situ testing in nearshore and oceanic environments. The instrument calibration includes (1)Selecting appropriate calibration buffer reagents according to the calibration requirements of seawater pH analysis; (2)Preparing calibration buffer system by replacing the commonly used 2-aminopyridine (AMP) solution with standard seawater. Data correction mainly includes temperature background correction and error correction. Insitu testing in the sea area and comparison with other similar instruments show that the error caused by the difference of calibration system can be up to 1.00 pH unit, and the data correction can improve the testing accuracy from 0.10 pH unit to 3.00 pH unit. The calibration and data correction method of the instrument can effectively improve the measurement accuracy of this self-developed pH sensor.

Abyssal peridotite is widely distributed in tectonic environments such as mid-ocean ridges, subduction zones, and continental margins, and typically undergoes subsequent alterations, among which serpentinization is the most significant type. Serpentinization refers to the chemical process wherein ferromagnesium-rich minerals in peridotite, such as olivine and pyroxene, are replaced by a series of secondary minerals like serpentine, magnetite, and brucite. The conditions of serpentinization are closely linked with hydrothermal circulation and the migration of mineral-forming substances, bearing significant implications for indicating hydrothermal mineralization. Traditional methods of petrology and geochemistry exhibit polysemic interpretations and uncertainties when reflecting serpentinization conditions, with different minerals or chemical indicators possibly suggesting different outcomes. Oxygen isotopes are ubiquitous in nature and the oxygen isotope tracing method, due to its wide applicability, ease of comparison, and support for in-situ micro-zone analysis, can clearly reflect the reaction conditions and processes of the mineral or rock-fluid system. This study primarily provides an overview of the principles of oxygen isotope thermometry, the process of abyssal peridotite serpentinization, application cases of oxygen isotope thermometry in the serpentinization of abyssal peridotite, factors influencing the oxygen isotope compositions of serpentinites, as well as the advantages and limitations of oxygen isotope thermometry. It aims to offer a reference for a more profound understanding of the serpentinization process of abyssal peridotite.